С.В. Шибанов, Д.А. Ягодников, В.И. Сарабьев, Г.А. Данилова, В.С. Качаун
10
Инженерный журнал: наука и инновации
# 10·2016
Regulation of the burning rate of a pyrotechnic
composition based on magnesium and sodium nitrate
additives of different type and particle size
© S.V. Shibanov
1
, D.A. Yagodnikov
2
, V.I. Sarabev
1
,
G.A. Danilova
1
, V.S. Kachaun
1
1
Research Institute of Applied Chemistry, Moscow Region, Sergiev Posad,
141313, Russia
2
Bauman Moscow State Technical University, Moscow, 105005, Russia
The article considers the results of influence of inorganic fluorides and iron oxide with
different dispersion on the burning characteristics of the pyrotechnic composition based
on magnesium and sodium nitrate. It shows the laws of burning rate of the studied com-
pounds depending on the type of the additive and the degree of increase the burning rate
using different additive content. It was established that under all other equal conditions
the effect of increasing of the burning rate under high pressure is mainly caused by the
increase of the exponent in the law of burning rate. The article also shows the ability to
control the burning rate by the appending of the necessary amount of additive
.
Keywords:
pyrotechnic composition, fluorides of metals, ultra- and nanodispersed pow-
ders, burning rate.
REFERENCES
[1]
Glaskov A.P.
Kataliz goreniya vzryvchatykh veshchestv
[Catalysis of explosives
burning]. Moscow, Nauka Publ., 1976, 264 p.
[2]
Silin N.A., Kashporov
L.Ya., Gladun V.D., Sheinmann L.E., Vaschenko V.A.
Shakhidzhanov E.S.
Goreniye metallizirovannykh geterogennykh konden-
sirovannykh system
[Burning of metallized heterogeneous condensed systems].
Moscow, Mashinostroenie Publ., 1982, 232 p.
[3]
Generalov M.B.
Kriokhimicheskaya nanotekhnologiya
[Cryochemical
nanotechnology]. Moscow, Akademkniga Publ., 2006, 325 p.
[4]
Pavlovets
G.Ya., Meleshko
V.Yu., Roschin A.V., Romanova I.P. Osobennosti
polucheniya nanoporoshkov elektrodugovoy plazmennoy perekondensatsiyey i
ikh diagnostiki [Features of nanopowder production by plasma arc
recondensation and diagnostics]. In:
Sb. materialov konf. “Plazmennyye
tekhnologii issledovaniya, modifikatsii i polucheniya materialov razlichnoy
fizicheskoy prirody”
[Coll. Conf. materials. "Plasma technology research,
modification and production of materials of various physical nature"]. Kazan,
KNRTU Publ., 2012, 396 p.
[5]
Rabinovich V.A., Khavin
Z.Ya.
Kratkiy khimicheskiy spravochnik
[A brief
chemical handbook]. A.A. Potekhina, A.I. Efimova, eds. Leningrad, Khimiya
Publ., 1991, 432 p.
[6]
Osnovnyye svoystva neorganicheskikh ftoridov. Spravochnik
[The basic
properties of inorganic fluorides. Handbook]. Moscow, Atomizdat Publ., 1975,
400 p.
[7]
Shibanov S.V., Kalinin S.V., Sarabev V.I., Shabunin A.I., Trutnev N.S. Vliyaniye
modifikatsii nanodispersnogo nitrata natriya na ballisticheskiye i tekhnologicheskiye
kharakteristiki vysokometallizirovannykh pirotekhnicheskikh system [Influence of
nanodispersed sodium nitrate modification on ballistic and technological