A comparative study on the influence of heating modes on the properties of cobalt and nickel nanopowders produced by the chemical-metallurgy method
Published: 29.03.2023
Authors: Tien Hiep Nguyen, Nguyen Van Minh, Nguyen Manh Hung, Nguyen Van Hoang, Nguyen Van Chuong, Do Van Minh, Tang Viet Phuong, Nguyen Viet Anh
Published in issue: #3(135)/2023
DOI: 10.18698/2308-6033-2023-3-2263
Category: Metallurgy and Science of Materials | Chapter: Powder Metallurgy and Composite Materials
The effect of heating modes on the properties of Co and Ni nanopowders obtained by the chemical-metallurgy method was compared. It was shown that all established heating modes (isothermal, non-isothermal and mixed) ensure the production of Co and Ni nanopowders with an average size of less than 100 nm, while the mixed regime makes it possible to obtain reduction products with the best characteristics in terms of dispersion and morphology.
References
[1] Bhushan B. Springer Handbook of Nanotechnology. 4th edition. Berlin, Springer-Verlag Heidelberg, 2017, 1500 p.
[2] Lyamkin S.A., Selivanov E.N., Semyonova N.S. Calculation of copper, nickel, and cobalt reduction rate with carbon monoxide out of oxide melts. Universities’ Proceedings. Non-Ferrous Metallurgy, 2014, (2), 26–29.
[3] Seong G., Takami S., Arita T., Minami K., Hojo D., Yavari A.R., Adschiri T. Supercritical hydrothermal synthesis of metallic cobalt nanoparticles and its thermodynamic analysis. The Journal of Supercritical Fluids, 2011, 60, 113–120.
[4] Farkas B., Santos-Carballal D., Cadi-Essadek A., De Leeuw N.H. A DFT+U study of the oxidation of cobalt nanoparticles: Implications for biomedical applications. Materialia, 2019, 7, 100381.
[5] Aydemir T., Golubeva N.D., Shershneva I.N., Kydralieva K.A., Dzhardimalieva G.I. Formation, structure and magnetic properties of nanocomposites obtained by Fe(III)Co(II) cocrystallized complexes thermal decomposition. Aerospace MAI Journal, 2019, 26 (2), 219–228.
[6] Nguyen T.H., Nguyen V.M. The effect of surfactants on the particle size of iron, cobalt and nickel nanopowders. Universities’ Proceedings. Powder Metallurgy and Functional Coatings, 2020, 1, 22–28.
[7] Li C., Wong L., Tang L., Scarlett N., Chiang K., Patel J., Burke N., Sage V. Kinetic modelling of temperature-programmed reduction of cobalt oxide by hydrogen. Appl. Catal. A, 2017, 537, 1–11.
[8] Dulina I., Lobunets T., Klochkov L., Ragulya A. Obtaining of Ni/NiO nanopowder from aqua solutions of Ni(CH3COO)2 ammonia complexes. Nanoscale Res. Lett., 2015, 10, 156.
[9] Banic S., Mahajan A. Size control synthesis of pure nickel nanoparticles and anodic-oxidation of Butan-1-ol in alkali. Mater. Chem. Phys., 2019, 235 (121), 747–756.
[10] Kesarla M.K., Reddy N.N.K., Ortiz-Chi F. Transformation of g-C3N4 into onion like carbon on nickel nanoparticles for ultrafast hydrogenation. Mater. Chem. Phys., 2020, 240 (122), 157–162.
[11] Jung K.Y., Lee J.H., Koo H.Y., Kang Y.C., Park S.B. Preparation of solid nickel nanoparticles by large-scale spray pyrolysis of Ni(NO3)2·6H2O precursor: Effect of temperature and nickel acetate on the particle morphology. Mater. Sci. Eng. B, 2007, 137 (1–3), 10–19.
[12] Nguyen T.H., Nguyen V.M., Danchuk V.N., Nguyen M.H., Nguyen H.V., Tang X.D. Kinetic characteristics of the process of synthesis of nickel nanopowder by the chemical metallurgy method. Nanotechnol. Russia, 2020, 15 (2), 146–152.
[13] Ryzhonkov D.I., Arsent’ev P.P., Yakovlev V.V. Theory of metallurgical processes. Moscow, Metallurgiya, 1989, 392 p.
[14] Brown M.E., Dollimore D., Galweys A.K. Reactions in the Solid State. Elsevier, Reading, 1980, 339 p.
[15] Schmalzried H. Chemical Kinetics of Solids. Weinheim, VCH, 1995, 433 p.
[16] Dzidziguri E.L., et al. Effect of cobalt production method on properties of its nanopowders. Bulletin of the Tomsk Polytechnic University, 2014, 324 (3), 7–15.
[17] Tikhomirov S.A. Patterns of consolidation of metallic nickel and iron nanopowders. Moscow, Baikov Institute of Metallurgy and Materials Science, RAS, 2007, 26 p.